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71.
Benzynes were generated from o-(trimethylsilyl)phenols using nonafluorobutanesulfonyl fluoride (NfF) by a domino process, i.e., the nonaflation of the phenolic hydroxyl group of o-(trimethylsilyl)phenols by NfF followed by the attack of the produced fluoride ion on the trimethylsilyl group. The generated benzyne immediately underwent various reactions to give polysubstituted benzenes. 相似文献
72.
73.
A total coloring of a graph G is a coloring of all elements of G, i.e. vertices and edges, such that no two adjacent or incident elements receive the same color. A graph G is s-degenerate for a positive integer s if G can be reduced to a trivial graph by successive removal of vertices with degree ≤s. We prove that an s-degenerate graph G has a total coloring with Δ+1 colors if the maximum degree Δ of G is sufficiently large, say Δ≥4s+3. Our proof yields an efficient algorithm to find such a total coloring. We also give a lineartime algorithm to find a total
coloring of a graph G with the minimum number of colors if G is a partial k-tree, that is, the tree-width of G is bounded by a fixed integer k. 相似文献
74.
75.
76.
Hisao Yamashige Shuji Matsuo Tsutomu Kurisaki Rupert C C Perera Hisanobu Wakita 《Analytical sciences》2005,21(3):309-314
X-ray absorption near edge structure (XANES) measurements at the C, N, and Fe K absorption edges were performed for iron(III)-tetraphenylporphyrin (FeTPP), iron(III)-tetrakis(p-carboxyphenyl)porphyrin (FeTCPP), and iron(III)-tetrakis(p-sulfonatophenyl)porphyrin (FeTSPP). The spectral shapes differ in the Fe K XANES, but not in C and N K XANES among FeTPP, FeTCPP, and FeTSPP. Crosschecks of XANES data for C, N, and Fe K absorption edges in combination with discrete variational (DV)-Xalpha molecular orbital (MO) calculations indicate that each p-electron-withdrawing group on four meso-phenyl substitutes in an Fe(III)-porphyrin complex brings about a unique electron state through the complex because of the electron-withdrawal strength, itself. Consequently, they affect the positive charge of the center Fe(III) ion. 相似文献
77.
Tomohisa Yamashita Shuji Kodama Mikiya Ohto Eriko Nakayama Sumiyo Hasegawa Nobutaka Takayanagi Tomoko Kemmei Akira Yamaguchi Norio Teramae Yukio Saito 《Analytical sciences》2006,22(12):1495-1500
The permeation fluxes of phenol, benzene sulfonate (BS) and benzene disulfonate (BDS) through a porous anodic alumina membrane with the perpendicularly oriented silica-surfactant nanochannel assembly membrane (NAM) were measured in water-ethanol mixture media. The permeation flux depended on solute charges and on solvent composition. As the ethanol ratio increased, the fluxes of BS and BDS increased and the flux of phenol decreased. The results of extraction/elution experiments also depended on the solute charges and the solvent composition. Chromatographic experiments in n-hexane showed that dipole and hydrophobic interactions affect the retention of solutes. Permeation of the solute across the NAM in water-ethanol mixture is likely to be determined by various factors such as dipole interaction, hydrophobic interaction, solvation, and anion-exchange efficiencies. 相似文献
78.
Hisao Yamashige Shuji Matsuo Tsutomu Kurisaki Rupert C C Perera Hisanobu Wakita 《Analytical sciences》2005,21(6):635-639
This study investigated the protonation of nitrogen atoms in porphyrins with meso-phenyl p-substituted by an electron-withdrawing group using N 1s X-ray photoelectron spectroscopy (XPS), the N K X-ray absorption near-edge structure (XANES), and the discrete variational (DV)-Xalpha molecular orbital (MO) method. Both tetraphenylporphyrin (TPP) and tetrakis(p-sulfonatophenyl)porphyrin (TSPP) have a single structure: the former has two protonated and two non-protonated N atoms in the porphine ring; the latter has four protonated N atoms in the porphine ring. In contrast, a combination of XPS, XANES, and DV-Xalpha MO calculations shows that tetrakis(p-carboxyphenyl)porphyrin (TCPP) has a dual structure: one structure has two protonated and two non-protonated N atoms; the other has four protonated N atoms. Furthermore, this result was also considered based on the protonation constants of N atoms in the porphyrins. The correlation between the strength of electron-withdrawing groups and protonation to N atoms in porphyrins can be described using the spectral patterns of the N 1s XPS and N K XANES spectra. 相似文献
79.
Shuji Saito 《Inventiones Mathematicae》1991,106(1):443-460
Oblatum 7-XI-1990 &; 25-III-1991 相似文献
80.
Koji Ishida Yoshiaki Uchida Shuji Ninomiya Masumi Osawa 《Fresenius' Journal of Analytical Chemistry》1990,336(5):419-422
Summary The thin-layer chromatographic behaviour of all the rare earths except Pm on silica gel in aqueous solutions of five alkali metal chlorides has been surveyed. The Rf-values and the logarithms of the separation factors relative to Gd vary in a regular and peculiar way with increasing atomic number, through a reflection of the strong tetrad effect. A discussion concerning the effects on the Rf-values of the solvent cations and the solvent anions, and typical chromatograms for the separations of multi-component mixtures containing adjacent lanthanoids are also presented. 相似文献